Data set GMTKN30_SCONF
relative energies of sugar conformers
The data set contains 17 items.
Downloads
Here you can download the data set definition file (in YAML format), an archive of the geometries and a dictionary file assigning the system names to the geometry file.
References
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Csonka, G. I.; French, A. D.; Johnson, G. P.; Stortz, C. A. J. Chem. Theory. Comput. 2009, 5, 679-692
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Goerigk, L.; Grimme S. J. Chem. Theory Comput. 2010, 6, 107-126.
Geometries
B3LYP/6-31+G*
Reference energies
CCSD(T)/CBS constructed from:
AnGol15 subset: MP2/aug-cc-pV(D->T)Z + dCCSD(T)/cc-pVDZ
GLC4 subset: MP2/aug-cc-pV(T->Q)Z + CCSD(T)/cc-pVTZ
Alternative reference data
The data set contains following sets of alternative reference values:
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HF/CBS
[L. Goerigk, S. Grimme, Phys. Chem. Chem. Phys., 2011, 13, 6670-6688.]
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MP2/CBS
[L. Goerigk, S. Grimme, Phys. Chem. Chem. Phys., 2011, 13, 6670-6688.]
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SCS-MP2/CBS
[L. Goerigk, S. Grimme, Phys. Chem. Chem. Phys., 2011, 13, 6670-6688.]