Data set A24
Accurate CCSD(T)/CBS interaction energies in small noncovalent complexes
The data set contains 24 items.
Downloads
Here you can download the data set definition file (in YAML format), an archive of the geometries and a dictionary file assigning the system names to the geometry file.
References
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Řezáč, J.; Hobza, P. J. Chem. Theory Comput. 2013, 9, 2151–2155.
Geometries
CCSD(T)/CBS, frozen core, counterpoise-corrected
MP2 extrapolated from aug-cc-pVTZ and aug-cc-pVQZ
dCCSD(T) in aug-cc-pVDZ
Reference energies
CCSD(T)/CBS, frozen core, counterpoise-corrected
3-point extrapolation from aug-cc-pVTZ, aug-cc-pVQZ and aug-cc-pV5Z
Groups
The data set is divided into following groups (by the type of the interaction):
- H-bond
- dispersion
- other
- stack
Alternative reference data
The data set contains following sets of alternative reference values:
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E1pol/aDZ
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E1exch/aDZ
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E2ind/aDZ
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E2ind_exch/aDZ
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E2disp/aDZ
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E2disp_exch/aDZ
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deltaHF/aDZ
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E1_sum/aDZ
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E2ind_sum/aDZ
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E2disp_sum/aDZ
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SAPT_E/aDZ
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E1pol/aTZ
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E1exch/aTZ
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E2ind/aTZ
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E2ind_exch/aTZ
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E2disp/aTZ
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E2disp_exch/aTZ
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deltaHF/aTZ
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E1_sum/aTZ
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E2ind_sum/aTZ
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E2disp_sum/aTZ
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SAPT_E/aTZ
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E1pol/aQZ
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E1exch/aQZ
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E2ind/aQZ
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E2ind_exch/aQZ
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E2disp/aQZ
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E2disp_exch/aQZ
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deltaHF/aQZ
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E1_sum/aQZ
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E2ind_sum/aQZ
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E2disp_sum/aQZ
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SAPT_E/aQZ
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E1pol/a5Z
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E1exch/a5Z
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E2ind/a5Z
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E2ind_exch/a5Z
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E2disp/a5Z
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E2disp_exch/a5Z
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deltaHF/a5Z
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E1_sum/a5Z
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E2ind_sum/a5Z
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E2disp_sum/a5Z
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SAPT_E/a5Z
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E2disp_sum/CBS
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SAPT_E/CBS